Abstract
The first examples of pyrazine-based gold(III) pincer complexes have been synthesized; their intense photoemissions can be modified by interactions with the non-coordinating pyrazine-N atom. Luminescence modulation is possible without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF)
| Original language | English |
|---|---|
| Pages (from-to) | 16629-16632 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 93 |
| Early online date | 2 Oct 2015 |
| DOIs | |
| Publication status | Published - 2015 |
Profiles
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Manfred Bochmann
- School of Chemistry, Pharmacy and Pharmacology - Emeritus Professor
- Chemistry of Light and Energy - Member
- Chemistry of Materials and Catalysis - Member
Person: Honorary, Research Group Member
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Garth Jones
- School of Chemistry, Pharmacy and Pharmacology - Associate Professor in Physical & Theoretical Chemistry
- Centre for Photonics and Quantum Science - Member
- Chemistry of Light and Energy - Member
Person: Research Group Member, Academic, Teaching & Research