Synthesis and Luminescence Modulation of Pyrazine-Based Gold(III) Pincer Complexes

Julio Fernandez Cestau, Benoît Bertrand, Maria Blaya, Garth A. Jones, Thomas J. Penfold (Lead Author), Manfred Bochmann

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Abstract

The first examples of pyrazine-based gold(III) pincer complexes have been synthesized; their intense photoemissions can be modified by interactions with the non-coordinating pyrazine-N atom. Luminescence modulation is possible without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF)
Original languageEnglish
Pages (from-to)16629-16632
JournalChemical Communications
Volume51
Issue number93
Early online date2 Oct 2015
DOIs
Publication statusPublished - 2015

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