Synthesis of crown ether-linked discotic triphenylenes

Juanjuan Li; Zhiqun He; Hemant Gopee; Andrew N. Cammidge

doi:10.1021/ol902637z

Synthesis of crown ether-linked discotic triphenylenes

Juanjuan Li, Zhiqun He, Hemant Gopee, Andrew N. Cammidge

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Novel triphenylene dimers linked by a central crown ether core have been synthesized and characterized. The crown ether is most conveniently formed as a final step to permit purification and isolation of ion-free material, and extension of the protocol permits synthesis of triad structures linked though a 27-crown-9 macrocycle. The latter compounds present a new discotic motif that supports mesophase formation.

Original language	English
Pages (from-to)	472-475
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/ol902637z
Publication status	Published - 2010

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10.1021/ol902637z

Cite this

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title = "Synthesis of crown ether-linked discotic triphenylenes",

abstract = "Novel triphenylene dimers linked by a central crown ether core have been synthesized and characterized. The crown ether is most conveniently formed as a final step to permit purification and isolation of ion-free material, and extension of the protocol permits synthesis of triad structures linked though a 27-crown-9 macrocycle. The latter compounds present a new discotic motif that supports mesophase formation.",

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AU - He, Zhiqun

AU - Gopee, Hemant

AU - Cammidge, Andrew N.

PY - 2010

Y1 - 2010

N2 - Novel triphenylene dimers linked by a central crown ether core have been synthesized and characterized. The crown ether is most conveniently formed as a final step to permit purification and isolation of ion-free material, and extension of the protocol permits synthesis of triad structures linked though a 27-crown-9 macrocycle. The latter compounds present a new discotic motif that supports mesophase formation.

AB - Novel triphenylene dimers linked by a central crown ether core have been synthesized and characterized. The crown ether is most conveniently formed as a final step to permit purification and isolation of ion-free material, and extension of the protocol permits synthesis of triad structures linked though a 27-crown-9 macrocycle. The latter compounds present a new discotic motif that supports mesophase formation.

U2 - 10.1021/ol902637z

DO - 10.1021/ol902637z

M3 - Article

VL - 12

SP - 472

EP - 475

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 3

ER -