Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis

Gareth Arnott; Harry Heaney; Roger Hunter; Philip C. Bulman Page

doi:10.1002/ejoc.200400615

Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis

Gareth Arnott, Harry Heaney, Roger Hunter, Philip C. Bulman Page

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantio selective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

Original language	English
Pages (from-to)	5126-5134
Number of pages	9
Journal	European Journal of Organic Chemistry
Issue number	24
DOIs	https://doi.org/10.1002/ejoc.200400615
Publication status	Published - 2004

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10.1002/ejoc.200400615

Cite this

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title = "Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis",

abstract = "Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantio selective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).",

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journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

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T1 - Synthesis of the first chiral, functionalised-bridged resorcinarenes in asymmetric catalysis: Evidence for intracavity asymmetric catalysis

AU - Arnott, Gareth

AU - Heaney, Harry

AU - Hunter, Roger

AU - Bulman Page, Philip C.

PY - 2004

Y1 - 2004

N2 - Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantio selective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

AB - Methodology is presented for synthesis of the first examples of chiral, bridged resorcinarenes with functionality in the bridge as possible sites for intracavity asymmetric catalysis. A preliminary study comparing unfunctionalised with functionalised lines using the enantio selective addition of diethylzinc to benzaldehyde as a probe reaction, provides compelling evidence for intracavity catalysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

U2 - 10.1002/ejoc.200400615

DO - 10.1002/ejoc.200400615

M3 - Article

SP - 5126

EP - 5134

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 24

ER -