Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes

Laurance R. Doyle; Peter J. Hill; Gregory Wildgoose; Andrew E. Ashley

doi:10.1039/C6DT00884D

Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes

Laurance R. Doyle, Peter J. Hill, Gregory Wildgoose, Andrew E. Ashley

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

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Abstract

The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, [Fe(dmpe2)2(μ-N2)]. For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.

Original language	English
Pages (from-to)	7550-7554
Journal	Dalton Transactions
Volume	45
Issue number	18
Early online date	5 Apr 2016
DOIs	https://doi.org/10.1039/C6DT00884D
Publication status	Published - 14 May 2016

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10.1039/C6DT00884DLicence: CC BY

c6dt00884dFinal published version, 755 KBLicence: CC BY

Frustrating Electrochemistry: Developing Electrocatalytic Frustrated Lewis Pairs
Wildgoose, G.
Royal Society
1/10/14 → 30/09/17
Project: Research
(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions
Wildgoose, G. & Blagg, R.
CEC (Framework 7)
1/08/12 → 31/07/17
Project: Research

Cite this

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abstract = "The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, [Fe(dmpe2)2(μ-N2)]. For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.",

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AU - Doyle, Laurance R.

AU - Hill, Peter J.

AU - Wildgoose, Gregory

AU - Ashley, Andrew E.

PY - 2016/5/14

Y1 - 2016/5/14

N2 - The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, [Fe(dmpe2)2(μ-N2)]. For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.

AB - The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, [Fe(dmpe2)2(μ-N2)]. For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.

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DO - 10.1039/C6DT00884D

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EP - 7554

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes

Abstract

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Projects

Frustrating Electrochemistry: Developing Electrocatalytic Frustrated Lewis Pairs

(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions

Cite this