The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate

Eddy Martin; David L. Hughes; Simon J. Lancaster

doi:10.1016/j.ica.2009.09.013

The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate

Eddy Martin, David L. Hughes, Simon J. Lancaster

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Treatment of LiC₆F₅ with B(C₆F₅)₃ in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt₂)₃][B(C₆F₅)₄]. Crystallization from diethyl ether yields solvent dependent [Li(OEt₂)₄][B(C₆F₅)₄], which has been crystallographically characterised.

Original language	English
Pages (from-to)	275-278
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	363
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2009.09.013
Publication status	Published - 2010

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10.1016/j.ica.2009.09.013

Cite this

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title = "The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate",

abstract = "Treatment of LiC6F5 with B(C6F5)3 in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt2)3][B(C6F5)4]. Crystallization from diethyl ether yields solvent dependent [Li(OEt2)4][B(C6F5)4], which has been crystallographically characterised.",

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journal = "Inorganica Chimica Acta",

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AU - Martin, Eddy

AU - Hughes, David L.

AU - Lancaster, Simon J.

PY - 2010

Y1 - 2010

N2 - Treatment of LiC6F5 with B(C6F5)3 in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt2)3][B(C6F5)4]. Crystallization from diethyl ether yields solvent dependent [Li(OEt2)4][B(C6F5)4], which has been crystallographically characterised.

AB - Treatment of LiC6F5 with B(C6F5)3 in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt2)3][B(C6F5)4]. Crystallization from diethyl ether yields solvent dependent [Li(OEt2)4][B(C6F5)4], which has been crystallographically characterised.

U2 - 10.1016/j.ica.2009.09.013

DO - 10.1016/j.ica.2009.09.013

M3 - Article

VL - 363

SP - 275

EP - 278

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 1

ER -