The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II)

Kathryn E. Toghill; Gregory Wildgoose; Amir Moshar; Chris Mulcahy; Richard G. Compton

doi:10.1002/elan.200804277

The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II)

Kathryn E. Toghill, Gregory Wildgoose, Amir Moshar, Chris Mulcahy, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

135 Citations (Scopus)

Abstract

We report the simultaneous electroanalytical determination of Pb²⁺ and Cd²⁺ by square-wave anodic stripping voltammetry (SWASV) using a bismuth nanoparticle modified boron doped diamond (Bi-BDD) electrode. Bi deposition was performed in situ with the analytes, from a solution of 0.1 mM Bi(NO₃)₃ in 0.1 M HClO₄ (pH 1.2), and gave detection limits of 1.9 µg L^-1 and 2.3 µg L^-1 for Pb(II) and Cd(II) respectively. Pb²⁺ and Cd²⁺ could not be detected simultaneously at a bare BDD electrode, whilst on a bulk Bi macro electrode (BiBE) the limits of detection for the simultaneous determination of Pb²⁺ and Cd²⁺ were ca. ten times higher.

Original language	English
Pages (from-to)	1731-1737
Number of pages	7
Journal	Electroanalysis
Volume	20
Issue number	16
DOIs	https://doi.org/10.1002/elan.200804277
Publication status	Published - Aug 2008

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10.1002/elan.200804277

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@article{47fa4b2755734f5db91ec3df453a5b24,

title = "The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II)",

abstract = "We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by square-wave anodic stripping voltammetry (SWASV) using a bismuth nanoparticle modified boron doped diamond (Bi-BDD) electrode. Bi deposition was performed in situ with the analytes, from a solution of 0.1 mM Bi(NO3)3 in 0.1 M HClO4 (pH 1.2), and gave detection limits of 1.9 µg L-1 and 2.3 µg L-1 for Pb(II) and Cd(II) respectively. Pb2+ and Cd2+ could not be detected simultaneously at a bare BDD electrode, whilst on a bulk Bi macro electrode (BiBE) the limits of detection for the simultaneous determination of Pb2+ and Cd2+ were ca. ten times higher.",

author = "Toghill, {Kathryn E.} and Gregory Wildgoose and Amir Moshar and Chris Mulcahy and Compton, {Richard G.}",

year = "2008",

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issn = "1040-0397",

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The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II). / Toghill, Kathryn E.; Wildgoose, Gregory; Moshar, Amir et al.

In: Electroanalysis, Vol. 20, No. 16, 08.2008, p. 1731-1737.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The fabrication and characterization of a bismuth nanoparticle modified boron doped diamond electrode and its application to the simultaneous determination of cadmium(II) and lead(II)

AU - Toghill, Kathryn E.

AU - Wildgoose, Gregory

AU - Moshar, Amir

AU - Mulcahy, Chris

AU - Compton, Richard G.

PY - 2008/8

Y1 - 2008/8

N2 - We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by square-wave anodic stripping voltammetry (SWASV) using a bismuth nanoparticle modified boron doped diamond (Bi-BDD) electrode. Bi deposition was performed in situ with the analytes, from a solution of 0.1 mM Bi(NO3)3 in 0.1 M HClO4 (pH 1.2), and gave detection limits of 1.9 µg L-1 and 2.3 µg L-1 for Pb(II) and Cd(II) respectively. Pb2+ and Cd2+ could not be detected simultaneously at a bare BDD electrode, whilst on a bulk Bi macro electrode (BiBE) the limits of detection for the simultaneous determination of Pb2+ and Cd2+ were ca. ten times higher.

AB - We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by square-wave anodic stripping voltammetry (SWASV) using a bismuth nanoparticle modified boron doped diamond (Bi-BDD) electrode. Bi deposition was performed in situ with the analytes, from a solution of 0.1 mM Bi(NO3)3 in 0.1 M HClO4 (pH 1.2), and gave detection limits of 1.9 µg L-1 and 2.3 µg L-1 for Pb(II) and Cd(II) respectively. Pb2+ and Cd2+ could not be detected simultaneously at a bare BDD electrode, whilst on a bulk Bi macro electrode (BiBE) the limits of detection for the simultaneous determination of Pb2+ and Cd2+ were ca. ten times higher.

U2 - 10.1002/elan.200804277

DO - 10.1002/elan.200804277

M3 - Article

VL - 20

SP - 1731

EP - 1737

JO - Electroanalysis

JF - Electroanalysis

SN - 1040-0397

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