The hafnium-mediated NH activation of an amido-borane

Elizabeth A. Jacobs; Anna-Marie Fuller; Simon J. Lancaster; Joseph A. Wright

doi:10.1039/c1cc11320h

The hafnium-mediated NH activation of an amido-borane

Elizabeth A. Jacobs, Anna-Marie Fuller, Simon J. Lancaster, Joseph A. Wright

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

Original language	English
Pages (from-to)	5870-5872
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	20
DOIs	https://doi.org/10.1039/c1cc11320h
Publication status	Published - 2011

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10.1039/c1cc11320h

Cite this

@article{e78aa774fcdb4c358ab1fda71a1e1b29,

title = "The hafnium-mediated NH activation of an amido-borane",

abstract = "Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.",

author = "Jacobs, {Elizabeth A.} and Anna-Marie Fuller and Lancaster, {Simon J.} and Wright, {Joseph A.}",

year = "2011",

doi = "10.1039/c1cc11320h",

language = "English",

volume = "47",

pages = "5870--5872",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

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T1 - The hafnium-mediated NH activation of an amido-borane

AU - Jacobs, Elizabeth A.

AU - Fuller, Anna-Marie

AU - Lancaster, Simon J.

AU - Wright, Joseph A.

PY - 2011

Y1 - 2011

N2 - Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

AB - Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

U2 - 10.1039/c1cc11320h

DO - 10.1039/c1cc11320h

M3 - Article

VL - 47

SP - 5870

EP - 5872

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 20

ER -