The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher Pickett, Xiaoming Liu

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    Abstract

    Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).
    Original languageEnglish
    Pages (from-to)3555-3557
    Number of pages3
    JournalChemical Communications
    Issue number30
    DOIs
    Publication statusPublished - 2008

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