The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher Pickett, Xiaoming Liu

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86 Citations (Scopus)

Abstract

Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).
Original languageEnglish
Pages (from-to)3555
Number of pages1
JournalChemical Communications
Issue number30
DOIs
Publication statusPublished - 2008

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