The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Xiufeng Wang; Zhimei Li; Xirui Zeng; Qiuyan Luo; David J. Evans; Christopher Pickett; Xiaoming Liu

doi:10.1039/b805262j

The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher Pickett, Xiaoming Liu

School of Chemistry

Research output: Contribution to journal › Article › peer-review

91 Citations (Scopus)

Abstract

Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).

Original language	English
Pages (from-to)	3555-3557
Number of pages	3
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b805262j
Publication status	Published - 2008

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10.1039/b805262j

Cite this

@article{82c22081944044a4a7fcdae20b724645,

title = "The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?",

abstract = "Infrared data for mono-iron complexes possessing two cis-CO together with M{\"o}ssbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).",

author = "Xiufeng Wang and Zhimei Li and Xirui Zeng and Qiuyan Luo and Evans, {David J.} and Christopher Pickett and Xiaoming Liu",

year = "2008",

doi = "10.1039/b805262j",

language = "English",

pages = "3555--3557",

journal = "Chemical Communications",

issn = "1359-7345",