The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(ii) or low-spin Fe(0)?

Xiufeng Wang, Zhimei Li, Xirui Zeng, Qiuyan Luo, David J. Evans, Christopher Pickett, Xiaoming Liu

Research output: Contribution to journalArticlepeer-review

94 Citations (Scopus)


Infrared data for mono-iron complexes possessing two cis-CO together with Mössbauer data for the enzyme and a model complex support the assignment that the iron centre of the cluster-free hydrogenase Hmd is low-spin Fe(II).
Original languageEnglish
Pages (from-to)3555-3557
Number of pages3
JournalChemical Communications
Issue number30
Publication statusPublished - 2008

Cite this