The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Fuquan Song; Roderick D. Cannon; Manfred Bochmann

doi:10.1039/b314845a

The kinetics of propene and hexene polymerisation with [(SBI)ZrR]⁺X⁻: evidence for monomer-dependent early or late transition states

Fuquan Song
, Roderick D. Cannon
, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

Original language	English
Pages (from-to)	542-543
Number of pages	2
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/b314845a
Publication status	Published - 5 Feb 2004

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10.1039/b314845a

Cite this

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title = "The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states",

abstract = "Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.",

author = "Fuquan Song and Cannon, \{Roderick D.\} and Manfred Bochmann",

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AU - Song, Fuquan

AU - Cannon, Roderick D.

AU - Bochmann, Manfred

PY - 2004/2/5

Y1 - 2004/2/5

N2 - Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

AB - Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

U2 - 10.1039/b314845a

DO - 10.1039/b314845a

M3 - Article

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EP - 543

JO - Chemical Communications

JF - Chemical Communications

IS - 5

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