The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Ramamoorthy Boomishankar; Joanne Ledger; Jean-Baptiste Guilbaud; Neil L. Campbell; John Bacsa; Richard Bonar-Law; Yaroslav Z. Khimyak; Alexander Steiner

doi:10.1039/b713847d

The N-donor stabilised cyclotriphosphazene hexacation [P₃N₃(DMAP)₆]⁶⁺

Ramamoorthy Boomishankar, Joanne Ledger, Jean-Baptiste Guilbaud, Neil L. Campbell, John Bacsa, Richard Bonar-Law, Yaroslav Z. Khimyak, Alexander Steiner

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

The cyclotriphosphazene P₃N₃Cl₆ reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P₃N₃(DMAP) ₆]Cl₆·19CHCl₃ comprising [P ₃N₃(DMAP)₆]⁶⁺ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Original language	English
Pages (from-to)	5152-5154
Number of pages	3
Journal	Chemical Communications
Issue number	48
Early online date	10 Oct 2007
DOIs	https://doi.org/10.1039/b713847d
Publication status	Published - 2007
Externally published	Yes

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title = "The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+",

abstract = "The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.",

author = "Ramamoorthy Boomishankar and Joanne Ledger and Jean-Baptiste Guilbaud and Campbell, {Neil L.} and John Bacsa and Richard Bonar-Law and Khimyak, {Yaroslav Z.} and Alexander Steiner",

year = "2007",

doi = "10.1039/b713847d",

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journal = "Chemical Communications",

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T1 - The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

AU - Boomishankar, Ramamoorthy

AU - Ledger, Joanne

AU - Guilbaud, Jean-Baptiste

AU - Campbell, Neil L.

AU - Bacsa, John

AU - Bonar-Law, Richard

AU - Khimyak, Yaroslav Z.

AU - Steiner, Alexander

PY - 2007

Y1 - 2007

N2 - The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

AB - The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

UR - http://www.scopus.com/inward/record.url?scp=36849089655&partnerID=8YFLogxK

U2 - 10.1039/b713847d

DO - 10.1039/b713847d

M3 - Article

AN - SCOPUS:36849089655

SP - 5152

EP - 5154

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 48

ER -

The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Abstract

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The N-donor stabilised cyclotriphosphazene hexacation [P₃N₃(DMAP)₆]⁶⁺