The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Ramamoorthy Boomishankar, Joanne Ledger, Jean-Baptiste Guilbaud, Neil L. Campbell, John Bacsa, Richard Bonar-Law, Yaroslav Z. Khimyak, Alexander Steiner

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Abstract

The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Original languageEnglish
Pages (from-to)5152-5154
Number of pages3
JournalChemical Communications
Issue number48
Early online date10 Oct 2007
DOIs
Publication statusPublished - 2007
Externally publishedYes

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