The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes

DA Pennington, DL Hughes, M Bochmann, SJ Lancaster

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Reaction between 3-But-2-(OSiMe3)C6H3CH=N(2,6-R2C6H3) (where R = H (1a) or Pri (1b)) and TiCl4(THF)2 affords the octahedral complexes Ti{3-But-2-(O)C6H3CH=N(2,6-R2C6H3)}Cl3(THF) while in the absence of THF 1b reacts with TiCl4 to give the binuclear complex [Ti{3-But-2-(O)C6H3CH=N(2,6-Pri2C6H3)}Cl(µ–Cl)3TiCl3]; the complexes give good productivities for ethene polymerisation when activated with MAO.
Original languageEnglish
Pages (from-to)3480-3482
Number of pages3
JournalDalton Transactions
Issue number18
DOIs
Publication statusPublished - 18 Aug 2003

Cite this