Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Philip C. Bulman Page, Hooshang Vahedi, Donald Bethell, James V. Barkley

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Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.
Original languageEnglish
Pages (from-to)1937-1941
Number of pages5
JournalSynthetic Communications
Volume33
Issue number11
DOIs
Publication statusPublished - 2003

Keywords

  • HYDROGEN-PEROXIDE
  • DBU
  • nucleophile
  • SULFIDES
  • CATALYTIC ASYMMETRIC OXIDATION

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