Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Philip C. Bulman Page; Hooshang Vahedi; Donald Bethell; James V. Barkley

doi:10.1081/scc-120020208

Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Philip C. Bulman Page, Hooshang Vahedi, Donald Bethell, James V. Barkley

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

10 Downloads (Pure)

Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

Original language	English
Pages (from-to)	1937-1941
Number of pages	5
Journal	Synthetic Communications
Volume	33
Issue number	11
DOIs	https://doi.org/10.1081/scc-120020208
Publication status	Published - 2003

Keywords

HYDROGEN-PEROXIDE
DBU
nucleophile
SULFIDES
CATALYTIC ASYMMETRIC OXIDATION

Access to Document

10.1081/scc-120020208

hoosh_DBU_reprint.pdfFinal published version, 173 KB

Cite this

@article{298cc30833a14090a0df9a69f3bca368,

title = "Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives",

abstract = "DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1{"}-azepin-2{"}-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.",

keywords = "HYDROGEN-PEROXIDE, DBU, nucleophile, SULFIDES, CATALYTIC ASYMMETRIC OXIDATION",

author = "{Bulman Page}, {Philip C.} and Hooshang Vahedi and Donald Bethell and Barkley, {James V.}",

year = "2003",

doi = "10.1081/scc-120020208",

language = "English",

volume = "33",

pages = "1937--1941",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis",

number = "11",

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T1 - Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

AU - Bulman Page, Philip C.

AU - Vahedi, Hooshang

AU - Bethell, Donald

AU - Barkley, James V.

PY - 2003

Y1 - 2003

N2 - DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

AB - DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

KW - HYDROGEN-PEROXIDE

KW - DBU

KW - nucleophile

KW - SULFIDES

KW - CATALYTIC ASYMMETRIC OXIDATION

U2 - 10.1081/scc-120020208

DO - 10.1081/scc-120020208

M3 - Article

VL - 33

SP - 1937

EP - 1941

JO - Synthetic Communications

JF - Synthetic Communications

SN - 0039-7911

IS - 11

ER -