Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Philip C. Bulman Page; Hooshang Vahedi; Donald Bethell; James V. Barkley

doi:10.1081/scc-120020208

Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Philip C. Bulman Page
, Hooshang Vahedi
, Donald Bethell
, James V. Barkley

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

12 Downloads (Pure)

Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

Original language	English
Pages (from-to)	1937-1941
Number of pages	5
Journal	Synthetic Communications
Volume	33
Issue number	11
DOIs	https://doi.org/10.1081/scc-120020208
Publication status	Published - 2003

Keywords

HYDROGEN-PEROXIDE
DBU
nucleophile
SULFIDES
CATALYTIC ASYMMETRIC OXIDATION

Access to Document

10.1081/scc-120020208

hoosh_DBU_reprint.pdfFinal published version, 173 KB

Cite this

@article{298cc30833a14090a0df9a69f3bca368,

title = "Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives",

abstract = "DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1{"}-azepin-2{"}-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.",

keywords = "HYDROGEN-PEROXIDE, DBU, nucleophile, SULFIDES, CATALYTIC ASYMMETRIC OXIDATION",

author = "\{Bulman Page\}, \{Philip C.\} and Hooshang Vahedi and Donald Bethell and Barkley, \{James V.\}",

year = "2003",

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language = "English",

volume = "33",

pages = "1937--1941",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis",

number = "11",

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T1 - Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

AU - Bulman Page, Philip C.

AU - Vahedi, Hooshang

AU - Bethell, Donald

AU - Barkley, James V.

PY - 2003

Y1 - 2003

N2 - DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

AB - DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

KW - HYDROGEN-PEROXIDE

KW - DBU

KW - nucleophile

KW - SULFIDES

KW - CATALYTIC ASYMMETRIC OXIDATION

U2 - 10.1081/scc-120020208

DO - 10.1081/scc-120020208

M3 - Article

SN - 0039-7911

VL - 33

SP - 1937

EP - 1941

JO - Synthetic Communications

JF - Synthetic Communications

IS - 11

ER -