Vibrational spectroscopic analysis of silicones: A Fourier transform-Raman and inelastic neutron scattering investigation

Linda Jayes; Andrew P. Hard; Christophe Séné; Stewart F. Parker; Upali A. Jayasooriya

doi:10.1021/ac026012f

Vibrational spectroscopic analysis of silicones: A Fourier transform-Raman and inelastic neutron scattering investigation

Linda Jayes, Andrew P. Hard, Christophe Séné, Stewart F. Parker, Upali A. Jayasooriya

School of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

An inelastic neutron scattering spectrum of a poly(dimethylsiloxane) (PDMS) is reported, and a spectrum simulated using a monomer molecular unit as a model for comparison. FT-Raman spectra of a series of PDMS derivatives are reported and structure spectra correlations are shown to exist for the estimation of (a) PDMS average chain length, (b) ratio of the number of monofunctional units to quadrifunctional units in silicone resins, and (c) the percentage weight of PDMS in silicone emulsions.

Original language	English
Pages (from-to)	742-746
Number of pages	5
Journal	Analytical Chemistry
Volume	75
Issue number	4
DOIs	https://doi.org/10.1021/ac026012f
Publication status	Published - 2003

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10.1021/ac026012f

Cite this

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title = "Vibrational spectroscopic analysis of silicones: A Fourier transform-Raman and inelastic neutron scattering investigation",

abstract = "An inelastic neutron scattering spectrum of a poly(dimethylsiloxane) (PDMS) is reported, and a spectrum simulated using a monomer molecular unit as a model for comparison. FT-Raman spectra of a series of PDMS derivatives are reported and structure spectra correlations are shown to exist for the estimation of (a) PDMS average chain length, (b) ratio of the number of monofunctional units to quadrifunctional units in silicone resins, and (c) the percentage weight of PDMS in silicone emulsions.",

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AU - Jayes, Linda

AU - Hard, Andrew P.

AU - Séné, Christophe

AU - Parker, Stewart F.

AU - Jayasooriya, Upali A.

PY - 2003

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AB - An inelastic neutron scattering spectrum of a poly(dimethylsiloxane) (PDMS) is reported, and a spectrum simulated using a monomer molecular unit as a model for comparison. FT-Raman spectra of a series of PDMS derivatives are reported and structure spectra correlations are shown to exist for the estimation of (a) PDMS average chain length, (b) ratio of the number of monofunctional units to quadrifunctional units in silicone resins, and (c) the percentage weight of PDMS in silicone emulsions.

U2 - 10.1021/ac026012f

DO - 10.1021/ac026012f

M3 - Article

VL - 75

SP - 742

EP - 746

JO - Analytical Chemistry

JF - Analytical Chemistry

SN - 0003-2700

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