Zinc(II) η1- and η2-toluene complexes: Structure and bonding in Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene)

Antonio Guerrero; Eddy Martin; David L. Hughes; Nikolas Kaltsoyannis; Manfred Bochmann

doi:10.1021/om060429k

Zinc(II) η¹- and η²-toluene complexes: Structure and bonding in Zn(C₆F₅)₂·(toluene) and Zn(C₆F₄-2-C₆F₅)₂·(toluene)

Antonio Guerrero, Eddy Martin, David L. Hughes, Nikolas Kaltsoyannis, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The first structural characterization of toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C₆F₅)₂·(toluene) and Zn(C₆F₄-2-C₆F₅)₂·(toluene) show toluene in ?² and ?¹ coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the toluene ring are rather similar in both cases.

Original language	English
Pages (from-to)	3311-3313
Number of pages	3
Journal	Organometallics
Volume	25
Issue number	14
DOIs	https://doi.org/10.1021/om060429k
Publication status	Published - 2006

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10.1021/om060429k

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@article{9eff2e2911c14ff0a503f59c9847708f,

title = "Zinc(II) η1- and η2-toluene complexes: Structure and bonding in Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene)",

abstract = "The first structural characterization of toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene) show toluene in ?2 and ?1 coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the toluene ring are rather similar in both cases.",

author = "Antonio Guerrero and Eddy Martin and Hughes, {David L.} and Nikolas Kaltsoyannis and Manfred Bochmann",

year = "2006",

doi = "10.1021/om060429k",

language = "English",

volume = "25",

pages = "3311--3313",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Zinc(II) η1- and η2-toluene complexes: Structure and bonding in Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene)

AU - Guerrero, Antonio

AU - Martin, Eddy

AU - Hughes, David L.

AU - Kaltsoyannis, Nikolas

AU - Bochmann, Manfred

PY - 2006

Y1 - 2006

N2 - The first structural characterization of toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene) show toluene in ?2 and ?1 coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the toluene ring are rather similar in both cases.

AB - The first structural characterization of toluene complexes of zinc is reported. The (perfluoroaryl)zinc compounds Zn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene) show toluene in ?2 and ?1 coordination modes, respectively. On the other hand, charge distribution calculations, Mulliken overlap population analysis, and bonding energy data suggest that the interactions between the Zn and the toluene ring are rather similar in both cases.

U2 - 10.1021/om060429k

DO - 10.1021/om060429k

M3 - Article

VL - 25

SP - 3311

EP - 3313

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 14

ER -